{"id":14357,"date":"2018-02-23T13:45:45","date_gmt":"2018-02-23T12:45:45","guid":{"rendered":"http:\/\/karmaka.de\/?p=14357"},"modified":"2018-02-23T13:45:45","modified_gmt":"2018-02-23T12:45:45","slug":"ultraviolet-spectral-reflectance-of-carbonaceous-materials","status":"publish","type":"post","link":"https:\/\/karmaka.de\/?p=14357","title":{"rendered":"Ultraviolet spectral reflectance of carbonaceous materials"},"content":{"rendered":"<p>Daniel M. Applin, Matthew R.M. Izawa, Edward A. Cloutis, Jeffrey J. Gillis-Davis, Karly M. Pitman, Ted L. Roush, Amanda R. Hendrix, Paul G. Lucey<\/p>\n<p>Icarus<br \/>\nVolume 307, June 2018, Pages 40\u201382<\/p>\n<p><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0019103517307881\" target=\"_blank\"><strong>LINK<\/strong><\/a><\/p>\n<p>&#8220;Highlights<\/p>\n<p>\u2022    The theory of ultraviolet reflectance of powders is reviewed.<br \/>\n\u2022    Previous ultraviolet reflectance experiments of carbon are reviewed.<br \/>\n\u2022    A database of carbon ultraviolet reflectance is constructed through experiment.<br \/>\n\u2022    Spectral-compositional-structural relationships are discussed.<br \/>\n\u2022    Brief interpretations of carbon-bearing planetary surfaces are discussed.&#8221;<\/p>\n<p>&#8220;A number of planetary spacecraft missions have carried instruments with sensors covering the ultraviolet (UV) wavelength range. However, there exists a general lack of relevant UV reflectance laboratory data to compare against these planetary surface remote sensing observations in order to make confident material identifications. To address this need, we have systematically analyzed reflectance spectra of carbonaceous materials in the 200\u2013500\u202fnm spectral range, and found spectral-compositional-structural relationships that suggest this wavelength region could distinguish between otherwise difficult-to-identify carbon phases. In particular (and by analogy with the infrared spectral region), large changes over short wavelength intervals in the refractive indices associated with the trigonal sp2\u03c0\u2013\u03c0* transition of carbon can lead to Fresnel peaks and Christiansen-like features in reflectance. Previous studies extending to shorter wavelengths also show that anomalous dispersion caused by the \u03c3\u2013\u03c3* transition associated with both the trigonal sp2 and tetrahedral sp3 sites causes these features below \u03bb\u202f=\u202f200\u202fnm. The peak wavelength positions and shapes of \u03c0\u2013\u03c0* and \u03c3\u2013\u03c3* features contain information on sp3\/sp2, structure, crystallinity, and powder grain size. A brief comparison with existing observational data indicates that the carbon fraction of the surface of Mercury is likely amorphous and submicroscopic, as is that on the surface of the martian satellites Phobos and Deimos, and possibly comet 67P\/Churyumov\u2013Gerasimenko, while further coordinated observations and laboratory experiments should refine these feature assignments and compositional hypotheses. The new laboratory diffuse reflectance data reported here provide an important new resource for interpreting UV reflectance measurements from planetary surfaces throughout the solar system, and confirm that the UV can be rich in important spectral information.&#8221;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Daniel M. Applin, Matthew R.M. Izawa, Edward A. Cloutis, Jeffrey J. Gillis-Davis, Karly M. Pitman, Ted L. Roush, Amanda R. Hendrix, Paul G. Lucey Icarus Volume 307, June 2018, Pages 40\u201382 LINK &#8220;Highlights \u2022 The&#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[9],"tags":[587,4388,3273,1479],"_links":{"self":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/14357"}],"collection":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=14357"}],"version-history":[{"count":1,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/14357\/revisions"}],"predecessor-version":[{"id":14358,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/14357\/revisions\/14358"}],"wp:attachment":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=14357"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=14357"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=14357"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}