{"id":14810,"date":"2018-05-18T20:30:35","date_gmt":"2018-05-18T18:30:35","guid":{"rendered":"http:\/\/karmaka.de\/?p=14810"},"modified":"2018-05-18T20:30:35","modified_gmt":"2018-05-18T18:30:35","slug":"sulfur-isotope-signatures-of-eucrites-and-diogenites","status":"publish","type":"post","link":"https:\/\/karmaka.de\/?p=14810","title":{"rendered":"Sulfur isotope signatures of eucrites and diogenites"},"content":{"rendered":"<p>Nanping Wu, James Farquhar, James W. Dottin III, Nivea Magalh\u00e3es<\/p>\n<p>Geochimica et Cosmochimica Acta,<br \/>\nVolume 233,15 July 2018,Pages 1-13<\/p>\n<p><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016703718302552\" target=\"_blank\"><strong>LINK<\/strong><\/a><\/p>\n<p>&#8220;High precision sulfur isotope data on eight eucrites and two diogenites are reported to explore the provenance of sulfur and processes that affected the sulfur isotope composition and sulfur abundance within the HED (Howardite, Eucrite, Diogenite) parent body (Asteroid 4 Vesta) or parent bodies for eucrite-like meteorites. Sulfur isotope values for a subset of six of the eucrites (EET 90020, PCA 82502, BTN 00300, MIL 11290, QUE 97014, and Sioux County) and two diogenites (Johnstown and Shalka) converge on a singular sulfur isotope composition, yielding a mean \u03b434S of 0.26\u202f\u00b1\u202f0.17\u2030 (2 SD), \u039433S of 0.010\u202f\u00b1\u202f0.007\u2030 (2 SD), and \u039436S of \u22120.22\u202f\u00b1\u202f0.21\u2030 (2 SD). The variances on these mean values can be entirely accounted for by analytical uncertainties. The homogenous positive \u039433S for these samples suggests that sulfur in Asteroid 4 Vesta has a \u039433S of 0.010\u202f\u00b1\u202f0.002\u2030 (2 SE) which is consistent with the occurrence of a process that allowed for promoted-isotopic-exchange within the parent body to homogenize \u039433S. This process was previously recognized in the homogenous \u039417O composition that has been linked to large-scale silicate melting and mixing. The positive \u03b434S of this group of samples is attributed to fractionations associated with sulfur loss, and the homogeneity of sulfur isotopes suggests that this loss predates the mixing event. The sulfur isotope data alone do not differentiate whether this loss occurred prior to or post core formation, or even prior to accretion.<\/p>\n<p>Two eucrites (GRA 98098 and CMS 04049) yield isotopic compositions that are distinct from this mean for \u03b434S, and in the case of CMS 04049, for \u039433S as well. GRA 98098 yields \u03b434S of 0.81\u202f\u00b1\u202f0.18\u2030 (2 \u03c3est, estimated external precision), \u039433S of 0.010\u202f\u00b1\u202f0.008\u2030 (2 \u03c3est) and \u039436S of 0.01\u202f\u00b1\u202f0.34\u2030 (2 \u03c3est). CMS 04049 yields \u03b434S of \u22120.22\u202f\u00b1\u202f0.18\u2030 (2 \u03c3est), \u039433S of 0.024\u202f\u00b1\u202f0.008\u2030 (2 \u03c3est), and \u039436S of \u22120.17\u202f\u00b1\u202f0.34\u2030 (2 \u03c3est). The more positive \u03b434S of GRA98098 suggests fractionation of sulfur (34S\/32S) by a combination of parent body processes that may be linked to evaporation. The more positive \u039433S and the negative \u03b434S of CMS 04049 suggests that this meteorite may be from another \u2018Vesta-like\u2019 parent body.&#8221;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Nanping Wu, James Farquhar, James W. Dottin III, Nivea Magalh\u00e3es Geochimica et Cosmochimica Acta, Volume 233,15 July 2018,Pages 1-13 LINK &#8220;High precision sulfur isotope data on eight eucrites and two diogenites are reported to explore&#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[36,35,33,186],"tags":[1824,1823,212,2118,1872],"_links":{"self":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/14810"}],"collection":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=14810"}],"version-history":[{"count":1,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/14810\/revisions"}],"predecessor-version":[{"id":14811,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/14810\/revisions\/14811"}],"wp:attachment":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=14810"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=14810"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=14810"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}