{"id":23381,"date":"2020-08-26T16:13:34","date_gmt":"2020-08-26T14:13:34","guid":{"rendered":"http:\/\/karmaka.de\/?p=23381"},"modified":"2020-08-26T16:13:47","modified_gmt":"2020-08-26T14:13:47","slug":"metal-silicate-silicon-isotopic-fractionation-and-the-composition-of-the-bulk-earth","status":"publish","type":"post","link":"https:\/\/karmaka.de\/?p=23381","title":{"rendered":"Metal-silicate silicon isotopic fractionation and the composition of the bulk Earth"},"content":{"rendered":"\n<p>Fr\u00e9d\u00e9ric Moynier, Zhengbin Deng, Ariane Lanteri, Rayssa Martins, Marc Chaussidon, Paul Savage, Julien Siebert<\/p>\n\n\n\n<p>Earth and Planetary Science Letters<br>Volume 549, 1 November 2020, 116468<\/p>\n\n\n\n<p><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0012821X2030412X\" target=\"_blank\" rel=\"noreferrer noopener\"><strong>LINK<\/strong><\/a><\/p>\n\n\n\n<p class=\"justify-text\">&#8220;The difference in the Si isotopic composition between the Earth and primitive meteorites had been used to constrain the amount of Si in the Earth&#8217;s core. However, there is presently a debate on the magnitude of the isotopic fractionation between metal and silicates as function of temperature based on experimental data. Here, we use a natural sample, an enstatite meteorite, Itqyi, as a natural experiment to determine an independent Si isotopic fractionation factor between metal and silicate. We determined the temperature of equilibrium between metal and silicate as well as the Si isotopic composition between the phases. We find that the dependence of Si isotopes with temperature to be:<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"399\" height=\"59\" src=\"http:\/\/karmaka.de\/wp-content\/uploads\/2020\/08\/x.jpg\" alt=\"\" class=\"wp-image-23382\" srcset=\"https:\/\/karmaka.de\/wp-content\/uploads\/2020\/08\/x.jpg 399w, https:\/\/karmaka.de\/wp-content\/uploads\/2020\/08\/x-300x44.jpg 300w\" sizes=\"(max-width: 399px) 100vw, 399px\" \/><\/figure>\n\n\n\n<p class=\"justify-text\">Using this dependence of the \u03b430Si with temperature we estimate the bulk Earth \u03b430Si as a function of Si content of the core for different plausible conditions. Even when using the most extreme parameters, we show that the bulk Earth must be isotopically heavier than any chondrites groups. We therefore confirm that core formation alone cannot account for the isotopic difference between the Earth and primitive meteorites. We show that there is no correlation between \u03b430Si and the Mg\/Si ratio suggesting that forsterite fractionation in the solar nebula may have had only a limited effect, if any. Our new results therefore confirm that volatility should have had a fundamental effect in shaping terrestrial planets chemical composition.&#8221;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Fr\u00e9d\u00e9ric Moynier, Zhengbin Deng, Ariane Lanteri, Rayssa Martins, Marc Chaussidon, Paul Savage, Julien Siebert Earth and Planetary Science LettersVolume 549, 1 November 2020, 116468 LINK &#8220;The difference in the Si isotopic composition between the Earth&#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[922,112,17,73],"tags":[80,3234,1813,5670,5017,2145,2192,1705],"_links":{"self":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/23381"}],"collection":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=23381"}],"version-history":[{"count":1,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/23381\/revisions"}],"predecessor-version":[{"id":23383,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/23381\/revisions\/23383"}],"wp:attachment":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=23381"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=23381"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=23381"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}