{"id":29713,"date":"2021-12-07T20:26:44","date_gmt":"2021-12-07T19:26:44","guid":{"rendered":"https:\/\/karmaka.de\/?p=29713"},"modified":"2021-12-07T21:18:16","modified_gmt":"2021-12-07T20:18:16","slug":"beckettite-ca2v6al6o20-a-new-mineral-in-a-type-a-refractory-inclusion-from-allende-and-clues-to-processes-in-the-early-solar-system","status":"publish","type":"post","link":"https:\/\/karmaka.de\/?p=29713","title":{"rendered":"Beckettite, Ca2V6Al6O20, a new mineral in a Type A refractory inclusion from Allende and clues to processes in the early solar system"},"content":{"rendered":"\n<p>Chi Ma, Alexander N. Krot, Julie Paque, Oliver Tschauner, Kazuhide Nagashima<\/p>\n\n\n\n<p>Meteoritics &amp; Planetary Science<br>Version of Record online: 07 December 2021<\/p>\n\n\n\n<p><a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1111\/maps.13771\" target=\"_blank\" rel=\"noreferrer noopener\"><strong>LINK<\/strong><\/a><\/p>\n\n\n\n<p class=\"justify-text\">&#8220;Beckettite (Ca2V6Al6O20; IMA 2015-001) is a newly discovered refractory mineral, occurring as micrometer-sized grains intergrown with hibonite and perovskite, and surrounded by secondary grossular, anorthite, coulsonite, hercynite, and corundum. It occurs within highly altered areas in a V-rich, Type A Ca-Al-rich inclusion (CAI), A-WP1, from the Allende CV3 carbonaceous chondrite. The type beckettite has an empirical formula of (Ca1.99Na0.01)(V3+3.47Al1.40Ti4+0.57Mg0.25Sc0.08Fe2+0.04)(Al5.72Si0.28)O20, with a triclinic structure in space group Purn1 and cell parameters a = 10.367 \u00c5, b = 10.756 \u00c5, c = 8.895 \u00c5, \u03b1 = 106.0\u00b0, \u03b2 = 96.0\u00b0, \u03b3 = 124.7\u00b0, V = 739.7 \u00c53, and Z = 2, which leads to a calculated density of 3.67 g cm\u22123. Beckettite\u2019s general formula is Ca2(V,Al,Ti,Mg)6Al6O20 and the endmember formula is Ca2V6Al6O20. Beckettite is slightly 16O-depleted (\u039417O = \u221216 \u00b1 2\u2030) compared to the coexisting hibonite and spinel \u221224 \u00b1 2\u2030. Beckettite is a primary high-temperature mineral resulting from igneous crystallization of an 16O-rich V-rich CAI melt together with V-bearing hibonite, perovskite, burnettite, spinel, and paqueite. Subsequently, beckettite experienced an incomplete isotope exchange with an 16O-poor aqueous fluid (\u039417O = \u22123 \u00b1 2\u2030) on the Allende parent asteroid.&#8221;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Chi Ma, Alexander N. Krot, Julie Paque, Oliver Tschauner, Kazuhide Nagashima Meteoritics &amp; Planetary ScienceVersion of Record online: 07 December 2021 LINK &#8220;Beckettite (Ca2V6Al6O20; IMA 2015-001) is a newly discovered refractory mineral, occurring as micrometer-sized&#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[66,14,2531],"tags":[108,6187,1846,3743,675],"_links":{"self":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/29713"}],"collection":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=29713"}],"version-history":[{"count":2,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/29713\/revisions"}],"predecessor-version":[{"id":29715,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/29713\/revisions\/29715"}],"wp:attachment":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=29713"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=29713"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=29713"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}