{"id":8574,"date":"2016-04-20T09:19:42","date_gmt":"2016-04-20T08:19:42","guid":{"rendered":"http:\/\/karmaka.de\/?p=8574"},"modified":"2016-04-20T09:21:01","modified_gmt":"2016-04-20T08:21:01","slug":"new-constraints-on-the-relationship-between-26al-and-oxygen-calcium-and-titanium-isotopic-variation-in-the-early-solar-system-from-a-multielement-isotopic-study-of-spinel-hibonite-inclusions","status":"publish","type":"post","link":"https:\/\/karmaka.de\/?p=8574","title":{"rendered":"New constraints on the relationship between 26Al and oxygen, calcium, and titanium isotopic variation in the early Solar System from a multielement isotopic study of spinel-hibonite inclusions"},"content":{"rendered":"<p>Levke K\u00f6\u00f6p, Daisuke Nakashima, Philipp R. Heck, Noriko T. Kita, Travis J. Tenner, Alexander N. Krot, Kazuhide Nagashima, Changkun Park, Andrew M. Davis<\/p>\n<p>Geochimica et Cosmochimica Acta<br \/>\nIn Press, Available online 20 April 2016<\/p>\n<p><a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016703716301776\" target=\"_blank\"><strong>LINK<\/strong><\/a><\/p>\n<p>&#8220;We report oxygen, calcium, titanium and 26Al-26Mg isotope systematics for spinel-hibonite inclusions (SHIBs), a class of calcium-aluminum-rich inclusions (CAI) common in CM chondrites. In contrast to previous studies, our analyses of 33 SHIBs and four SHIB-related objects obtained with high spatial resolution demonstrate that these CAIs have a uniform \u039417O value of approximately \u201323\u2030, similar to many other mineralogically pristine CAIs from unmetamorphosed chondrites (e.g., CR, CV, and Acfer 094). Five SHIBs studied for calcium and titanium isotopes have no resolvable anomalies beyond 3\u03c3 uncertainties. This suggests that nucleosynthetic anomalies in the refractory elements had been significantly diluted in the environment where SHIBs with uniform \u039417O formed. We established internal 26Al-26Mg isochrons for eight SHIBs and found that seven of these formed with uniformly high levels of 26Al (a multi-CAI mineral isochron yields an initial 26Al\/27Al ratio of \u223c4.8\u00d710\u20135), but one SHIB has a smaller initial 26Al\/27Al of \u223c2.5\u00d710\u20135, indicating variation in 26Al\/27Al ratios when SHIBs formed. The uniform calcium, titanium and oxygen isotopic characteristics found in SHIBs with both high and low initial 26Al\/27Al ratios allow for two interpretations. (1) If subcanonical initial 26Al\/27Al ratios in SHIBs are due to early formation, as suggested by Liu et al. (2012), our data would indicate that the CAI formation region had achieved a high degree of isotopic homogeneity in oxygen and refractory elements before a homogeneous distribution of 26Al was achieved. (2) Alternatively, if subcanonical ratios were the result of 26Al-26Mg system resetting, the clustering of SHIBs at a \u039417O value of \u223c \u201323\u2030 would imply that a 16O-rich gaseous reservoir existed in the nebula until at least \u223c0.7 Ma after the formation of the majority of CAIs.&#8221;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Levke K\u00f6\u00f6p, Daisuke Nakashima, Philipp R. Heck, Noriko T. Kita, Travis J. Tenner, Alexander N. Krot, Kazuhide Nagashima, Changkun Park, Andrew M. Davis Geochimica et Cosmochimica Acta In Press, Available online 20 April 2016 LINK&#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[66,18,72,65],"tags":[238,332,2734,1846,2736,105,2733,2227,2732,2735],"_links":{"self":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/8574"}],"collection":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=8574"}],"version-history":[{"count":1,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/8574\/revisions"}],"predecessor-version":[{"id":8575,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/8574\/revisions\/8575"}],"wp:attachment":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=8574"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=8574"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=8574"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}