{"id":9476,"date":"2016-07-22T14:50:42","date_gmt":"2016-07-22T12:50:42","guid":{"rendered":"http:\/\/karmaka.de\/?p=9476"},"modified":"2016-07-22T14:50:42","modified_gmt":"2016-07-22T12:50:42","slug":"rare-earth-element-minerals-in-martian-breccia-meteorites-nwa-7034-and-7533-implications-for-fluid-rock-interaction-in-the-martian-crust","status":"publish","type":"post","link":"https:\/\/karmaka.de\/?p=9476","title":{"rendered":"Rare-earth-element minerals in martian breccia meteorites NWA 7034 and 7533: Implications for fluid\u2013rock interaction in the martian crust"},"content":{"rendered":"<p>Yang Liu, Chi Ma, John R. Beckett, Yang Chen, Yunbin Guan<\/p>\n<p>Earth and Planetary Science Letters<br \/>\nIn Press, Corrected Proof, Available online 21 July 2016<\/p>\n<p><a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0012821X16303284\" target=\"_blank\"><strong>LINK<\/strong><\/a><\/p>\n<p>&#8220;Highlights<br \/>\n\u2022    Martian meteorite NWA 7034\/7533 contains monazite, xenotime, chevkinite-perrierite.<br \/>\n\u2022    These REE-minerals are likely formed by hydrothermal alterations of their source rocks.<br \/>\n\u2022    Wide-spread hydrothermal event(s) likely occurred in the Martian crust at >1 Ga.&#8221;<\/p>\n<p>&#8220;Paired martian breccia meteorites, Northwest Africa (NWA) 7034 and 7533, are the first martian rocks found to contain rare-earth-element (REE) phosphates and silicates. The most common occurrence is as clusters of anhedral monazite-(Ce) inclusions in apatite. Occasionally, zoned, irregular merrillite inclusions are also present in apatite. Monazite-bearing apatite is sometimes associated with alkali-feldspar and Fe-oxide. Apatite near merrillite and monazite generally contains more F and OH (F-rich region) than the main chlorapatite host and forms irregular boundaries with the main host. Locally, the composition of F-rich regions can reach pure fluorapatite. The chlorapatite hosts are similar in composition to isolated apatite without monazite inclusions, and to euhedral apatite in lithic clasts. The U\u2013Th-total Pb ages of monazite in three apatite are View the MathML source1.0\u00b10.4Ga (2\u03c3  ), View the MathML source1.1\u00b10.5Ga (2\u03c3  ), and View the MathML source2.8\u00b10.7Ga (2\u03c3), confirming a martian origin. The texture and composition of monazite inclusions are mostly consistent with their formation by the dissolution of apatite and\/or merrillite by fluid at elevated temperatures (>100\u2009\u00b0C).<\/p>\n<p>In NWA 7034, we observed a monazite-chevkinite-perrierite-bearing benmoreite or trachyandesite clast. Anhedral monazite and chevkinite-perrierite grains occur in a matrix of sub-micrometer REE-phases and silicates inside the clast. Monazite-(Ce) and -(Nd) and chevkinite-perrierite-(Ce) and -(Nd) display unusual La and Ce depletion relative to Sm and Nd. In addition, one xenotime-(Y)-bearing pyrite-ilmenite-zircon clast with small amounts of feldspar and augite occurs in NWA 7034. One xenotime crystal was observed at the edge of an altered zircon grain, and a cluster of xenotime crystals resides in a mixture of alteration materials. Pyrite, ilmenite, and zircon in this clast are all highly altered, zircon being the most likely source of Y and HREE now present in xenotime. The association of xenotime with zircon, low U and Th contents, and the low Yb content relative to Gd and Dy in xenotime suggest the possible formation of xenotime as a byproduct of fluid\u2013zircon reactions.<\/p>\n<p>On the basis of relatively fresh apatite grains and lithic clasts in the same samples, we propose that the fluid\u2013rock\/mineral reactions occurred in the source rocks before their inclusion in NWA 7034 and 7533. Additionally, monazite-bearing apatite and REE-mineral-bearing clasts are possibly derived from different crustal origins. Thus, our results imply the wide-occurrence of hydrothermal fluids in the martian crust at 1 Ga or older, which were probably induced by impacts or large igneous intrusions.&#8221;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Yang Liu, Chi Ma, John R. Beckett, Yang Chen, Yunbin Guan Earth and Planetary Science Letters In Press, Corrected Proof, Available online 21 July 2016 LINK &#8220;Highlights \u2022 Martian meteorite NWA 7034\/7533 contains monazite, xenotime,&#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[42,46],"tags":[183,352],"_links":{"self":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/9476"}],"collection":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=9476"}],"version-history":[{"count":1,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/9476\/revisions"}],"predecessor-version":[{"id":9477,"href":"https:\/\/karmaka.de\/index.php?rest_route=\/wp\/v2\/posts\/9476\/revisions\/9477"}],"wp:attachment":[{"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=9476"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=9476"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/karmaka.de\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=9476"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}