Raman spectroscopy of Ryugu particles and their extracted residues: Fluorescence background characteristics and similarities to CI chondrites
Mutsumi Komatsu, Hikaru Yabuta, Yoko Kebukawa, Lydie Bonal, Eric Quirico, Timothy J. Fagan, George D. Cody, Jens Barosch, Laure Bejach, Emmanuel Dartois, Alexandre Dazzi, Bradley De Gregorio, Ariane Deniset-Besseau, Jean Duprat, Cecile Engrand, Minako Hashiguchi, Zita Martins, Jérémie Mathurin, Gilles Montagnac, Smail Mostefaoui, Larry R. Nittler, Takuji Ohigashi, Taiga Okumura, Laurent Rémusat, Scott Sandford, Rhonda Stroud, Hiroki Suga, Yoshio Takahashi, Yasuo Takeichi, Yusuke Tamenori, Maximilien Verdier-Paoletti, Shohei Yamashita, Hisayoshi Yurimoto, Tomoki Nakamura, Takaaki Noguchi, Ryuji Okazaki, Hiroshi Naraoka, Kanako Sakamoto, Makoto Yoshikawa, Takanao Saiki, Satoshi Tanaka, Fuyuto Terui, Satoru Nakazawa, Tomohiro Usui, Masanao Abe, Tatsuaki Okada, Toru Yada, Masahiro Nishimura, Aiko Nakato, Akiko Miyazaki, Kasumi Yogata, Shogo Tachibana, Sei-ichiro Watanabe, Yuichi Tsuda
MAPS, Version of Record online: 04 July 2024
“We present here an investigation of Ryugu particles recovered by the Hayabusa2 space mission and their extracted carbonaceous acid residues using Raman spectroscopy. Raman parameters of Ryugu intact grains and their acid residues are characterized by broad D (defect induced) and G (graphite) band widths, indicating the presence of polyaromatic carbonaceous matter with low thermal maturity. Raman spectra of Ryugu particles and CI (type 1) chondrites exhibit stronger laser-induced fluorescence backgrounds compared to Type 2 and Type 3 carbonaceous chondrites. The high fluorescence signatures and wide bandwidths of the D and G bands of Ryugu intact grains are similar to the Raman spectra observed in CI chondrites, reflecting the low structural order of their aromatic carbonaceous matter, and strengthening the link between Ryugu particles and CI chondrites. The high fluorescence background intensity of the Ryugu particles is due to multiple causes, but it is likely that the relative abundance of geometry-bearing macromolecular organic matter in total organic carbon contents makes a large contribution to the fluorescence intensities. Locally observed high fluorescence in the acid-extracted residues of Ryugu is due to nitrogen-bearing outlier phase. The high fluorescence signature is one consequence of the low degree of thermal maturity of the organic matter and supports evidence that the Ryugu particles have escaped significant parent body thermal metamorphism.”
