Characterizing the spectral, microstructural, and chemical effects of solar wind irradiation on the Murchison carbonaceous chondrite through coordinated analyses
D.L. Laczniak, M.S. Thompson, R. Christoffersen, C.A. Dukes, S.J. Clemett, R.V. Morris, L.P. Keller
In Press, Journal Pre-proof, Available online 17 April 2021
• Solar wind irradiation of carbon-rich asteroids simulated using 1 keV/amu H+- and He+-irradiation of the Murchison carbonaceous chondrite.
• XPS analyses are consistent with the removal of surface carbon and chemical reduction of iron from ion irradiation.
• VNIR analyses show brightening (longward of ~0.80 μm) and reddening from He+-irradiation.
• μL2MS analyses suggest that H+-irradiation increases the abundance of some low-molecular-weight free organic species (likely with bulk organic content staying constant), He+-irradiation decreases the bulk organic content, and both types of ion irradiation increase H2O and OH− content.
• TEM analyses indicate complete amorphization of matrix phyllosilicates, partial amorphization of olivine, vesiculation, and chemical heterogeneity in ion-affected rims.”
“We performed H+ and He+ ion irradiation experiments on slabs of the Murchison CM2 meteorite to simulate solar wind irradiation of carbonaceous asteroids. Two separate 6 mm × 6 mm regions were irradiated with 1 keV H+ and 4 keV He+, respectively, to fluences of 8.1 × 1017 ions/cm2 for H+ and 1 × 1018 ions/cm2 for He+. Unirradiated and irradiated surfaces were analyzed using X-ray photoelectron spectroscopy (XPS), visible to near infrared spectroscopy (VNIR; 0.35–2.5 μm), and microprobe two-step laser-desorption mass spectrometry (μL2MS). We also performed analytical field-emission scanning transmission electron microscopy (FE-STEM) of focused ion beam (FIB) cross-sections extracted from olivine grains and matrix material within the H+- and He+-irradiated regions. In situ XPS analyses suggest that ion irradiation results in the removal of most surface carbon and the partial reduction of surface iron to lower oxidation states. In response to He+-irradiation, we observed reddening and brightening of reflectance spectra, which is a departure from typical lunar-style space weathering. Additionally, H+- and He+-irradiation have opposing effects on organic carbon content: H+-irradiation increases the abundance of some free organic species by breaking down macromolecular material while He+-irradiation causes a decrease in overall organic content by cleaving bonds and sputtering constituent atoms. This suggests that solar wind H+-irradiation and solar wind He+-irradiation change the organic functional group chemistry of asteroidal regolith in different ways. In contrast to some previous experimental space weathering studies, we observe an increase in H2O and OH− abundances in our sample in response to both types of ion irradiation. FE-STEM and energy dispersive X-ray spectroscopy (EDX) analyses show complete amorphization of matrix phyllosilicates in ion-affected rims, partial amorphization of olivine, and changes in Si and Mg concentrations at and/or near the surface. We discuss the implications of these results for understanding the complex nature of space weathering of primitive, carbon-rich asteroids and for analyzing future returned samples from carbonaceous asteroids Bennu and Ryugu.”