A Direct View of the Chemical Properties of Water from Another Planetary System: Water D/H in 3I/ATLASOPEN ACCESS 

Luis E. Salazar Manzano, Teresa Paneque-Carreño, Martin A. Cordiner, Edwin A. Bergin, Hsing Wen Lin, Dariusz C. Lis, David W. Gerdes, Jennifer B. Bergner, Nicolas Biver, Dominique Bockelée-Morvan, Dennis Bodewits, Steven B. Charnley, Jacques Crovisier, Davide Farnocchia, Viviana V. Guzmán, Stefanie N. Milam, John W. Noonan, Anthony J. Remijan, Nathan X. Roth, John J. Tobin

Submitted to Nature Astronomy

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“All detected water reservoirs in the solar system exhibit a deuterium enrichment that links back to the physical environment at the time of stellar birth. Gas-phase and ice-grain D-enrichments occur through chemical processes that operate at low temperatures (< 30 K) pointing towards an origin in the pre-stellar molecular cloud or in the outer parts of the protoplanetary disk. However, not all stars are born in environments similar to our Sun, nor do their subsequent evolutionary histories follow the same path. These environmental differences can be traced by the water D/H ratio. Here we use ALMA observations of the interstellar comet 3I/ATLAS to constrain the water D/H ratio in extrasolar cometary material. With a water D/H value of [D/H]H2 O > 6.6 × 10−3, 3I/ATLAS shows a deuterium enrichment exceeding Earth’s ocean value by more than a factor of ≳ 40 and typical Solar System cometary values by more than a factor of ≳ 30. The elevated deuterium enrichment points to water that formed under colder, less irradiated conditions and from less thermally processed material, consistent with an origin in a planetary system that formed under different physical and chemical conditions than our own.”