Mineralogical and isotopic constraints on early, high-temperature events and reservoirs recorded in the interior of a Type B Ca-Al-rich inclusion from the reduced CV3 chondrite VigaranoOPEN ACCESS
Jangmi Han, Changkun Park, Ming-Chang Liu, Nozomi Matsuda, Justin I. Simon, Lindsay P. Keller
Geochimica et Cosmochimica Acta
In Press, Journal Pre-proof, Available online 24 July 2025
“A coordinated mineralogical and oxygen and Al-Mg isotopic study of a Type B Ca-Al-rich inclusion (CAI) from the reduced CV3 chondrite Vigarano was carried out using electron microprobe analysis, transmission electron microscopy, and secondary ion mass spectrometry. This CAI, a once molten igneous object, shows heterogeneous oxygen isotopic compositions among its constituent mineral phases. Spinel is uniformly 16O-rich with Δ17O ≤ −23 ‰. The Δ17O values of Al,Ti-diopside in the CAI core range from −11 ‰ to −18 ‰, which are positively correlated with its TiO2 contents, whereas diopside in the Wark–Lovering (WL) rim is 16O-rich with Δ17O = −23 ‰. Melilite in the CAI mantle shows Δ17O values ≤ −10 ‰ only when Åk<15 but becomes more 16O-poor (Δ17O = −3 ‰ to −9 ‰) when Åk>15. These correlated chemical and oxygen isotopic variations were likely established during crystallization of melilite and Al,Ti-diopside from a partial melt, while spinel preserves the original 16O-rich composition of the CAI precursor. We infer that a partial melt was isotopically evolving from 16O-rich to 16O-poor during melilite crystallization, then back to 16O-rich during Al,Ti-diopside crystallization via exchange with different gas reservoirs of 16O-poor and 16O-rich compositions during heating event(s). Our Al-Mg isotopic measurements of the CAI core and mantle define a single isochron with an inferred initial 26Al/27Al ratio of (4.93 ± 0.18) × 10−5, indistinguishable from that of the WL rim. This indicates that multiple high-temperature events and oxygen isotope exchange with isotopically distinct gas reservoirs occurred rapidly during the CAI formation.”
