A Fluid-Mediated Alteration Process on the Howardite Parent Asteroid Recorded by Pyroxene Decomposition to Fe–Ti–Cr Oxides and Amorphous Silica
Lilin Huang, Yanxue Wu, Riqiang Wen, Chunwen Huang, Chunmei Li, Jiangmin Ma
JGR Planets, First published: 03 August 2026
“In this study, we report amorphous silica dendrites in three eucritic pyroxene grains from a howardite meteorite NWA 14701. These textures exhibit enhanced metasomatic features characterized by irregular or rounded amorphous silica containing numerous nanoscale ilmenite and chromian ulvöspinel inclusions distributed along both sides of fractures to form dendritic networks in the host pyroxene. These dendritic networks manifest as a discontinuous series of discrete, equant-shaped silica masses that project as embayments into the walls of the fractures. We propose that the formation mechanism of these amorphous silica dendrites was related to fluid-mediated alteration processes, as recorded by pyroxene decomposition to Fe–Ti–Cr oxides and amorphous silica along fractures. Such fluid preferentially leached and removed highly mobile cations (e.g., Mg, Ca, and Fe). Concomitantly, high field-strength elements (Cr and Ti) with extremely low mobility became passively enriched in situ due to their limited transportability within the fluid phase, subsequently crystallizing as ilmenite and chromian ulvöspinel at nanoscale dimensions. Meanwhile, the Si-O framework of the original host pyroxene, depleted in most interstitial cations, was preserved as a chemically inert amorphous silica framework. Our work suggests that the amorphous silica dendrites represent an unique type of secondary alteration texture on the HED parent asteroid that was previously undocumented, and they may also occur on other airless, differentiated planetary bodies.”
